Product ID:1503 ANTIQUE WHITE DECORATOR PAINTS
MSDS Date:12/01/1996
FSC:NIIN:Submitter:D DG
Status Code:A
MSDS Number: CKVNJ

SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC

31500 SOLON ROAD
SOLON, OH 44139
US

Emergency Phone: 216-566-2917

Info Phone: 800-247-3270; 800-832-2541

Cage: TO019

SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC

SOLON, OH 44139 US

Telephone: 800-247-3270; 216-566-2917

Cage: TO019

PROPANE

CAS: 74-98-6

RTECS: TX2275000

OSHA PEL 1800 MG/M3;1000 PPM

BUTANE

CAS: 106-97-8

RTECS: EJ4200000

ACGIH TLV: 1900 MG/M3;800 PPM

ACETONE

CAS: 67-64-1

RTECS: AL3150000

OSHA PEL 2400 MG/M3;1000 PPM

ACGIH TLV: 1780 MG/M3;750 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ETHYLBENZENE

CAS: 100-41-4

RTECS: DA0700000

OSHA PEL 435 MG/M3;100 PPM

ACGIH TLV: 434 MG/M3;100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENE

CAS: 1330-20-7

RTECS: ZE2100000

ACGIH TLV: 434 MG/M3;100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1-BUTANOL

CAS: 71-36-3

RTECS: EO1400000

OSHA PEL 300 MG/M3;100 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHYL ETHYL KETONE

CAS: 78-93-3

RTECS: EL6475000

OSHA PEL 590 MG/M3;200 PPM

ACGIH TLV: 590 MG/M3;200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHYL ISOBUTYL KETONE

CAS: 108-10-1

RTECS: SA9275000

OSHA PEL 410 MG/M3;100 PPM

ACGIH TLV: 205 MG/M3;50 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

1-METHOXY-2-PROPANOL ACETATE

CAS: 108-65-6

RTECS: AI8925000

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

OSHA PEL 15 MG/M3

ACGIH TLV: 10 MG/M3

Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:IRRITATION OF EYES, SKIN AND
RESPIRATORY SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME
OVEREXPOSURE MAY RESULT IN UNCONSCIOUSNESS AND POSSIBLY DEATH.
CHRONIC: PROLONGED OVEREXPOSURE TO SOLVENT INGREDIENTS MAY CAUSE
ADVERSE EFFECTS TO LIVER, URINARY, BLOOD-FORMING, CARDIOVASCULAR &
REPRODUCTIVE SYSTEMS. METHYL ETHYL KRTONE MAY INCREASE THE NERVOUS
SYSTEM EFFECTS OF OTHER SOLVENTS. METHYL ETH YL KETONE MAY INCREASE
THE NERVOUS SYSTEM EFFECTS OF OTHER SOLVENTS. REPORTS HAVE
ASSOCIATED REPEATED OR PROLONGED OVEREXPOSURE TO SOLVENTS WITH
PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE.
Explanation of Carcinogenicity:NO INGREDIENT IN THESE PRODUCTS IS AN
IARC, NTP OR OSHA LISTED CARCINOGEN.
Effects of Overexposure:HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF
COORDINATION ARE INDICATIONS OF EXCESSIVE EXPOSURE TO VAPORS OR
SPRAY MISTS. TENDERNESS AND ITCHING OR BURNING SENSATION MAY
INDICATE EYE OR EXCESSIVE SKIN EXP OSURE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:IF INHALED: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE
BREATHING. KEEP WARM AND QUIET. IF ON SKIN: WASH AFFECTED AREA
THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
LAUNDER BEFORE RE USE. IF IN EYES: FLUSH WITH LARGE AMOUNTS OF
WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. IF SWALLOWED: NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO NOT INDUCE
VOMITING. GIVE CONSCIOUS PA TIENT SEVERAL GLASSES OF WATER. SEEK
MEDICAL ATTENTION.

Flash Point Method:PMCC
Flash Point:<-17.6C, 0.F
Lower Limits:1.0
Upper Limits:13.1
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING
SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED. WATER SPRAY MAY
BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WATER
MAY BE USED TO COOL CLOSED CO NTAINERS TO PREVENT PRESSURE BUILD-UP
AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME
HEAT.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. ISOLATE FROM
HEAT, ELECTRICAL EQUIPMENT, SPARKS & OPEN FLAME. APPLICATION TO HOT
SURFACES REQUIRES SPECIAL PRE CAUTIONS. DURING EMERGENCY CONDITIONS
OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & OPEN
FLAME. VAPORS WILL ACCUMULATE READILY & MAY IGNITE EXPLOSIVELY.
DURING USE & UNTIL ALL VAPORS ARE GONE. KEEP AREA VENTILATED-DO NOT
SMOKE-EXTINGUISH ALL FLAMES, PILO T LIGHTS & HEATERS -TURN OFF
STOVES, ELECTRIC TOOLS & APPLIANCES, ANY OTHER SOURCES OF IGNITION.
Other Precautions:CONSULT NFPA CODE. USE APPROVED BONDING & GROUNDING
PROCEDURES. CONTENTS UNDER PRESSURE. DO NOT PUNCTURE, INCINERATE,
OR EXPOSE TO TEMPERATURE ABOVE 120F. HEAT FROM SUNLIGHT, RADIATORS,
STOVES, HOT WA TER, & OTHER HEAT SOURCES COULD CAUSE CONTAINERS TO
BURST. DO NOT TAKE INTERNALLY. KEEP OUT OF THE R EACH OF CHILDREN.

Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA FOR PROTECTION
AGAINST INGREDIENTS. WHEN SANDING OR ABRADING THE DRIED FILM,
WEAR A DUST/MIST RESPIRATOR APPROVED BY NIOSH/MSHA FOR DUST WHICH
MAY BE GENERATED FROM THIS PRODUCT.
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE
EXPOSURE TO MATERIALS IN SECTION II IS MAINTAINED BELOW APPLICABLE
EXPOSURE LIMITS.
Protective Gloves:NONE REQUIRED FOR NORMAL APPLICATION OF AEROSOL
PRODUCTS .
Eye Protection:SAFETY SPECTACLES WITH UNPERFORATED SIDESHIELDS.
Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE
REUSE.
Supplemental Safety and Health
INTENTIONAL MISUSE OF DELIBERATELY CONCENTRATING AND INHALING THE
CONTENTS CAN BE HARMFUL OR FATAL.

HCC:V3
Boiling Pt:B.P. Text:<0 - 302F
Vapor Density:>AIR
VOC Grams/Liter:2.95
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:COLOR: WHITE.

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS IN INGREDIENTS.

Waste Disposal Methods:DO NOT INCINERATE. DEPRESSURIZE CONTAINER.
DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS
REGARDING POLLUTION.

Toxicological Information:RATS EXPOSED TO TITANIUM DIOXIDE DUST AT 250
MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH PRESSURE ELEVELS ARE NOT
ATTAINABLE IN THE WORKPLACE. . WEIGHT PER GALLONS (LBS.): 6.71. VOC
AS A PERCENT BY WEI GHT PER BAAQMD & CARB :43.9.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

SARA Title III Information:INGREDIENTS SUBJECT TO THE REPORTING
REQUIREMENTS OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT
(SARA) SECTION 313. 40 CFR 372.65 C: ETHYLBENZENE, XYLENE,
1-BUTANOL, METHYL ETHYL KETONE & METHYL ISOBUTYL KETONE.
Federal Regulatory Information:TSCA CERTIFICATION: ALL CHEMICALS IN
THESE PRODUCTS ARE LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA
INVENTORY.
State Regulatory Information:WARNING: THESE PRODUCTS CONTAIN A
CHEMICAL/S KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.